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981.
Malte Thoma Christoph Mayer Klaus Grosfeld 《Earth and Planetary Science Letters》2008,269(1-2):242-247
Subglacial lakes provide unique habitats, but the exact nature of physical and geochemical conditions are still a matter of debate and await direct sampling of water. Due to its isolation from external atmospheric forcing other environmental parameters influence the flow characteristics within the lake. In this study we use an improved treatment of the physical processes at the ice–water boundary interface to identify and quantify the impact of (1) the geothermal heat flux, (2) the heat flux from the lake into the ice, (3) the influence of the salinity of the lake water, and (4) the ice thickness on the size of the freezing area and the freeze/melt rates. We show that the modelled basal mass imbalance (that is the produced melt water minus the re-frozen water) depends on the geothermal heating as well as the heat flux into the ice. The circulation and the temperature distribution within subglacial Lake Vostok are rather stable against variations of geothermal heat flux, heat flux into the ice sheet, salinity of the lake, and small changes of the ice thickness above the lake. However, the flow regime for any subglacial lake with less than 2000 m ice thickness above, will be substantially different from those that experience higher pressures. This is because the buoyancy–temperature relationship reverses at this depth. 相似文献
982.
983.
L.?C.?BaldwinEmail author F.?Tomaschek C.?Ballhaus A.?Gerdes R.?O.?C.?Fonseca R.?Wirth T.?Geisler T.?Nagel 《Contributions to Mineralogy and Petrology》2017,172(6):43
Megacrystic sapphires are frequently associated with alkaline basalts, most notably in Asia and Australia, although basalt is not generally normative in corundum. Most of these sapphire occurrences are located in alluvial or eluvial deposits, making it difficult to study the enigmatic relationship between the sapphires and their host rocks. Here, we present detailed petrological and geochemical investigations of in situ megacrystic sapphires within alkaline basalts from the Cenozoic Siebengebirge Volcanic Field (SVF) in Germany. Markedly, the sapphires show several micrometer thick spinel coronas at the contact with the host basalt, indicating chemical disequilibrium between the sapphire and the basaltic melt, supporting a xenogenetic relationship. However, in situ U–Pb dating of a Columbite Group inclusion within one Siebengebirge sapphire using laser ablation–inductively coupled plasma–mass spectrometry (LA–ICP–MS) indicates a close genetic relationship between sapphire crystallization and alkaline mafic volcanism in the SVF. The syngenetic mineral inclusion suite including carbonates, members of the Pyrochlore, Betafite and Columbite Groupe minerals, as well as a high abundance of HFSE and of gaseous low-density CO2 inclusions support a parentage of a highly evolved, MgO and FeO deficient carbonatitic melt. We identified CO2 to be the link between alkaline basaltic volcanism and the xenocrystic sapphires. Only alkaline volcanic suites can build up enough CO2 in this magma chamber upon fractionation so that at high degrees of fractionation a carbonatitic melt exsolves which in turn can crystallize sapphires. 相似文献
984.
193nm ArF准分子激光系统对LA-ICP-MS分析中不同基体的剥蚀行为和剥蚀速率探究 总被引:7,自引:6,他引:1
探究LA-ICP-MS分析中不同基体的剥蚀行为和剥蚀速率,可为激光参数设定、基体匹配选择、数据质量保证等方面提供重要参考。本文研究了193 nm ArF准分子激光系统对人工合成/地质样品玻璃、常见矿物和粉末压片的剥蚀行为,同时探究了激光参数(束斑直径、能量密度和剥蚀频率)对剥蚀速率的影响情况。从剥蚀坑形貌可知,193nm ArF激光对玻璃和绝大多数矿物的剥蚀行为良好,但对石英相对较差,这可能与石英内含有微观包裹体,剥蚀过程中局部受热不均有关。粉末压片的剥蚀行为呈现出不可控,可通过提高粉末压片的压制压力或降低粉末颗粒的粒径来改善剥蚀行为;当剥蚀深度大于1.5倍束斑直径时,剥蚀速率随剥蚀深度的增加而逐渐减小,剥蚀深度最多可达束斑直径的两倍左右(RESOlution M-50型号激光系统,3.0 J/cm2激光能量密度);剥蚀速率随激光能量密度的增加而增大,但基本不受剥蚀频率(2~20 Hz)影响。不同基体具有特征的剥蚀速率,本文报道了43种基体的剥蚀速率参数,总体而言,NIST系列玻璃的剥蚀速率大于地质样品玻璃,碳酸盐矿物和硫化物矿物大于硅酸岩矿物,粉末压片大于玻璃和常见矿物。 相似文献
985.
Klaus Regenauer-Lieb David A. Yuen Florian Fusseis 《Pure and Applied Geophysics》2009,166(10-11):1885-1908
The total rate of rock deformation results from competing deformation processes, including ductile and brittle mechanisms. Particular deformation styles arise from the dominance of certain mechanisms over others at different ambient conditions. Surprisingly, rates of deformation in naturally deformed rocks are found to cluster around two extremes, representing coseismic slip rates or viscous creep rates. Classical rock mechanics is traditionally used to interpret these instabilities. These approaches consider the principle of conservation of energy. We propose to go one step further and introduce a nonlinear far-from-equilibrium thermodynamic approach in which the central and explicit role of entropy controls instabilities. We also show how this quantity might be calculated for complex crustal systems. This approach provides strain-rate partitioning for natural deformation processes occurring at rates in the order of 10-3 to 10-9 s-1. We discuss these processes using examples of landslides and ice quakes or glacial surges. We will then illustrate how the mechanical mechanisms derived from these near-surface processes can be applied to deformation near the base of the seismogenic crust, especially to the phenomenon of slow earthquakes. 相似文献
986.
Cristina?PulidoEmail author Kaj?Sand-Jensen Esther?C.?H.?E.?T.?Lucassen Jan?G.?M.?Roelofs Klaus?P.?Brodersen Ole?Pedersen 《Aquatic Sciences - Research Across Boundaries》2012,74(2):351-360
Isoetids, as indicators of near-pristine softwater lakes, have a high priority in national and international (European Water
Directive Framework) assessments of ecological lake quality. Our main goal was to identify the most important environmental
factors that influence the composition of plant communities and specifically determine the presence and abundance of the isoetid
Lobelia dortmanna in NW European softwater lakes. Geographical position and composition of surface water, porewater, sediment and plant communities
were examined in 39 lakes in four regions (The Netherlands, Denmark, West Norway and East Norway) distributed over a 1,200-km
long distance. We confirmed that lake location was accompanied by significant changes in environmental variables between NW
European lakes. Lake location was the single most important determinant of vegetation composition and it had significant individual
contributions independent of the coupling to environmental variables. This influence of location was supported by a significant
decline of community similarity with geographical distance between pairs of lakes at regional, inter-regional and international
scales. Combining the geographical position with environmental variables for surface water, porewater and sediment significantly
improved prediction of vegetation composition. Specifically, the combination of latitude, surface water alkalinity, porewater
phosphate and redox potential offered the highest correlation (BIO ENV correlation 0.66) to vegetation composition. This complex
analysis can also account for high sediment variability in the littoral zone of individual lakes, by using site-specific physico-chemical
sediment factors, and offer better predictions of vegetation composition when lake water chemistry is relatively homogeneous
among lakes within regions. 相似文献
987.
Much attention has recently been devoted to the fate and effects of pharmaceuticals in the water cycle. Removal of antibiotics in effluents by photo‐treatment or biodegradation is a topic currently under discussion. Degradation and removal efficiencies of sulfisomidine (SUI) by photodegradation and aerobic biodegradability were studied. SUI behavior was monitored during photolysis and photocatalysis (catalyst titanium dioxide) using 150‐W medium‐pressure Hg lamp. Also an aerobic bacterial degradation test from the OECD series (closed bottle test (CBT, OECD 301 D)) was performed. The primary elimination of SUI was monitored. Structures of photo‐degradation products were assessed by chromatographic separation on a C18 column with ultraviolet detection at 270 nm and ion trap MS. The results demonstrate that SUI is not readily biodegradable in CBT. Photo catalysis was more is effective than photolysis. SUI underwent photodegradation and several SUI photoproducts were identified. Accordingly, the photodegradation pathway of SUI was postulated. When reaching the aquatic environment, SUI and its photo products can constitute a risk to the environment. 相似文献
988.
989.
Gaël Cazes David Fink Alexandru T. Codilean Réka-Hajnalka Fülöp Toshiyuki Fujioka Klaus M. Wilcken 《地球表面变化过程与地形》2020,45(2):424-439
We use cosmogenic 10Be and 26Al in both bedrock and fluvial sediments to investigate controls on erosion rates and sediment supply to river basins at the regional scale in the Kimberley, NW Australia. The area is characterised by lithologically controlled morphologies such as cuestas, isolated mesas and extensive plateaus made of slightly dipping, extensively jointed sandstones. All sampled bedrock surfaces at plateau tops, ridgelines, and in the broader floodplain of major rivers over the region show similar slow lowering rates between 0.17 and 4.88 m.Myr-1, with a mean value of 1.0 ± 0.6 m.Myr-1 (n=15), whilst two bedrock samples collected directly within river-beds record rates that are one to two orders of magnitude higher (14.4 ± 1.5 and 20.9 ± 2.5 m.Myr-1, respectively). Bedrock 26Al/10Be ratios are all compatible with simple, continuous sub-aerial exposure histories. Modern river sediment yield lower 10Be and 26Al concentrations, apparent 10Be basin-wide denudation rates ranging between 1.8 and 7.7 m.Myr-1, with a median value of 2.6 m.Myr-1, more than double the magnitude of bedrock erosion rates. 26Al/10Be ratios of the sediment samples are lower than those obtained for bedrock samples. We propose that these depleted 26Al/10Be ratios can largely be explained by the supply of sediment to river basins from the slab fragmentation and chemical weathering of channel gorge walls and plateau escarpments that result in diluting the cosmogenic nuclide concentration in river sediments measured at the basin outlets. The results of a mass-balance model suggest that ~60–90% of river sediment in the Kimberley results from the breakdown and chemical weathering of retreating vertical sandstone rock-walls in contrast to sediment generated by bedrock weathering and erosion on the plateau tops. This study emphasises the value of analysing two or more isotopes in basin-scale studies using cosmogenic nuclides, especially in slowly eroding post-orogenic settings. © 2019 John Wiley & Sons, Ltd. 相似文献
990.